Thermodynamic and Technological Compatibility of Polyvinyl Chloride, Thermoplastic Polyurethane, and Bio-Plasticizer Blends

Polymer blending enhances material properties by combining different polymers, which requires careful consideration of both thermodynamic and technological compatibility. This study investigates the compatibility of polyvinyl chloride (PVC), thermoplastic polyurethane (TPU), and a bio-plasticizer in blends produced via roll milling at various mixing ratios. Compatibility and morphology were analyzed using thermally stimulated discharge (TSD), dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM), while mechanical and thermal properties were assessed by mechanical testing and thermogravimetric analysis (TGA). The PVC/TPU (100/30) blend exhibited superior phase compatibility over PVC/TPU (100/50), as indicated by a single relaxation peak in TSD and DMA, along with a more homogeneous morphology and enhanced tensile properties. The PVC/TPU/bio-plasticizer (100/20/50) blend showed a well-balanced mechanical performance and improved phase homogeneity. The TSD peak maxima trends for the TPU/bio-plasticizer blend highlighted the bio-plasticizer’s dual role in enhancing flexibility at low concentrations while restricting molecular mobility at higher concentrations. TGA revealed TPU’s positive effect on PVC’s degradation profile, while the bio-plasticizer reduced thermal stability. These findings demonstrate that blending PVC, TPU, and bio-plasticizer creates compatible materials with enhanced and diverse properties, making them suitable for industrial applications.