This study introduces a novel approach to optimize the weldability of AlSi‐coated press‐hardened 22MnB5 steel, focusing on the effects of preheating treatment on the coating microstructure. Despite extensive research on heat treatment during hot stamping, the impact of preheating prior to resistance spot welding on the coating structure and welding quality remains unexplored. By analyzing the evolution of coating microstructure at various preheating temperatures and durations, unique phase transformations within the AlSi coating are revealed, with altering composition and sheet resistance. Below 750 °C, limited Fe diffusion retains a high‐AlSi layer (0.0031 Ω). As preheating temperature increases, the diffusion rate of Fe atoms within the coating gradually increases, transitioning the coating structure to a three‐layer α‐Fe/Fe 2 Al 5 /α‐Fe, with a resistance value of 0.6312 Ω, 200 times higher than that without preheating. Tensile shear load increases with preheating temperature up to 950 °C, where optimized nugget size and martensitic transformation enhance joint strength. However, excessive preheating (1050 °C) causes nugget expulsion, reducing performance. This study not only advances the understanding of preheating treatment in AlSi‐coated steels, but also provides a strategy for enhancing weldability in lightweight automotive manufacturing.