Sustainable engineered geopolymer composites incorporating recycled waste rubber as full replacement of fine aggregates

材料科学 聚合物 复合材料 天然橡胶 橡胶屑 废物管理 抗压强度 工程类
作者
Feihong Wan,Yutao Guo,Miaozi Zheng,Binbin Li,A.Y. Elghazouli
出处
期刊:Journal of materials research and technology [Elsevier BV]
卷期号:37: 5614-5641 被引量:14
标识
DOI:10.1016/j.jmrt.2025.07.153
摘要

Recycled waste rubber from end-of-life tyres offers a sustainable alternative to natural aggregates in construction materials. Most existing studies have however typically limited the rubber replacement ratios to below 30 % (by volume) due to the associated strength reduction. This study addresses this limitation by developing rubberised engineered geopolymer composites (RU-EGCs) in which fine silica sand (FSS) is replaced by high volume of rubber (0 %, 30 %, 60 %, and 100 %), aiming to simultaneously improve ductility and sustainability. A detailed experimental evaluation is conducted in this study through mechanical testing, microstructural characterisation, and life cycle assessment (LCA), for understanding the fundamental performance of RU-EGCs. The results show that increasing the rubber replacement ratio reduces the compressive strength yet markedly improves the ductility and crack control. The fully rubberised mixture is shown to achieve a tensile strain of 7.7 % and maintains a compressive strength of 47 MPa. X-ray computed tomography (X-CT) and backscattered electron (BSE) imaging analyses also reveal increased porosity and a wider interfacial transition zone (ITZ) with rubber incorporation, which facilitate early crack initiation. Nevertheless, strong fibre/matrix bonding ensures sufficient bridging stress and energy dissipation, hence promoting a transition toward high ductility. Moreover, the LCA results demonstrate notable environmental benefits whereby, compared to typical engineered cementitious composites (ECC), the developed RU-EGCs achieves more than 40 % reduction in both embodied carbon and material cost. Overall, the findings of this investigation lays down an approach for designing sustainable ultra-high-ductility EGC through high-volume rubber utilisation, offering strong potential for practical application. • Engineered geopolymer composites (EGC) was developed using full-scale rubber replacement for fine silica sand. • Hybrid modification with rubber and fibres enabled ultra-high ductility (≥6 %). • Rubber incorporation significantly improved crack control ability. • The developed EGC exhibited lower embodied carbon, embodied energy, and material cost to remarkable extents.

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