化学
烟气脱硫
浸出(土壤学)
石膏
氨
碳化作用
无机化学
有机化学
冶金
材料科学
环境科学
土壤科学
土壤水分
作者
Xinhui Zhu,Yuan Gong,Baizhi Wu,Hongxia Wei,Chunlei Li
出处
期刊:Journal of physics
[IOP Publishing]
日期:2023-07-01
卷期号:2539 (1): 012072-012072
标识
DOI:10.1088/1742-6596/2539/1/012072
摘要
Abstract As an industrial by-product of flue gas desulfurization, flue gas desulfurization gypsum (FGD gypsum), whose main component is CaSO 4 · 2H 2 O, is an ideal raw material for mineralization. The technical problem of indirect mineralization lies in the efficient recycling of leaching agents, while amino acids have the lowest solubility at their isoelectric point, and thus the mixture of amino acids can be separated by adjusting the isoelectric point. Therefore, this paper proposes the use of aspartic acid (ASP) as leaching agent to realize the recycling of leaching agent. The leaching efficiency of Ca 2+ was regulated by changing the temperature, liquid-to-solid ratio, ammonia concentration, and the ratio of ASP to the amount of FGD gypsum substance. The results showed that ASP could sufficiently improve the leaching efficiency of Ca 2+ from desulfurized gypsum under alkaline conditions provided by ammonia. The leaching concentration of Ca 2+ was 7474.92 mg/L at 7% ammonia concentration, temperature of 30 °C, n (ASP) : n (FGD gypsum) = 2.5:1, and liquid-solid ratio of 30:1 mL/g, which was 12 times higher compared with the leaching concentration of Ca 2+ in pure water of 601.2 mg/L. While improving the leaching efficiency, ASP has lone electron pairs and can form soluble complexes with Ca 2+ under alkaline environment, which can convert the crystalline form of the product CaCO 3 to sphalerite during the mineralization process, and can regenerate ASP by adding acid to adjust the pH, and the recovery rate can reach 80.72%. This method effectively solves the problem of resource waste caused by the massive accumulation of desulfurization gypsum.
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