In this paper, the effects of process parameters on the absorption rate of P for hypereutectic Al-Si alloy (A390) which modified with Cu-14%P master alloy were systematically studied. And the mechanism that the process parameters play a role in effecting on the absorption rate of P was deeply investigated. The results indicated that the absorption rate of P increased with the increase of modified time and temperature, and decreased with the increase of the amount of added P. Under the same process condition, P added in form of Cu-14%P particles can cause to obtain the higher absorption rate of P than that of Cu-14%P powders. According to the experimental results, an equation on changes of the absorption rate of P was proposed, and the results show that good agreement is obtained between calculated and experimental values. The process parameters played a role in effecting on the absorption rate of P mainly through affecting the reaction rate of forming AlP particles in the melt, as well as the degree of reaction reached.