饱和(图论)
螯合作用
水溶液中的金属离子
丝绸
材料科学
吸光度
金属
滤纸
丝胶
化学工程
离子
植物螯合素
纳米技术
分析化学(期刊)
化学
色谱法
复合材料
冶金
有机化学
工程类
酶
组合数学
谷胱甘肽
数学
作者
Liang Yao,Minglu Hao,Feng Zhao,Yilin Wang,Yueru Zhou,Zhongyi Liu,Xiaofan An,Zhong Feng Gao,Jun Wang,Tao Zheng,Pu Chen,Lei Zhang
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2022-01-01
卷期号:14 (46): 17277-17289
被引量:12
摘要
Silk sericin (SS) is a natural water-soluble protein with the potential to chelate metal ions via its polar groups. However, the difficulty of identifying the saturation of SS limits its application as filter films. One solution is to construct SS filter films with an indicator to reflect the degree of saturation of silk sericin. Hence, the nanocoating consisting of co-assembled SS protein and anthocyanin (C3G) nanoparticles is designed, constructed, and characterized to chelate metal ions with a saturation-visualization detection behavior. Here, metal ions Zn2+ and Al3+ are chosen as models to explore the chelating ability of SS and indicator behaviors of C3G, which could indicate the saturation degree of SS. Interestingly, after the saturation of SS in the solution and filter film situations, the visible color progressively shifts from pink to blue (Zn2+) or violet (Al3+), with the corresponding redshift of UV-Vis absorbance of C3G. Remarkable removal effectiveness of Zn2+ and Al3+, namely 93.16% and 53.97%, as well as an evident saturation-visualization detection, were identified by filter paper films with the nanocoating. Our research provides a fresh viewpoint for designing SS filter films that could effectively remove metal ions while enabling real-time viewing.
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