A fire-retardant coating for wood made from chitosan itaconate

阻燃剂 材料科学 壳聚糖 涂层 复合材料 高分子科学 化学工程 法律工程学 工程类
作者
Nils Münstermann,Oliver Weichold
出处
期刊:Progress in Organic Coatings [Elsevier BV]
卷期号:197: 108793-108793 被引量:11
标识
DOI:10.1016/j.porgcoat.2024.108793
摘要

Wood is becoming increasingly popular again due to an increased environmental awareness. However, wood generally needs protection from a number of external influences such as moisture, UV, stains, and also fire. The latter is a particular challenge for building materials because once ignited, untreated wood usually burns down completely without the need for a continuous external heat supply. We have recently developed a sustainable coating based on polymerised chitosan itaconate, which protects wood against moisture, UV, and stains. Free-standing chitosan itaconate films were now found to be non-flammable and do not melt when exposed to fire. Thermogravimetric analyses of these films underscore the importance of polymerisation to increase the thermal stability. When applied to wood surfaces, the coating delays the ignition and the spreading of flames. A single application already reduces the burning rate by one third. With multiple layers of the coating, the samples extinguish as soon as the external flame is removed. • Sustainable coating: Fully bio-based, biodegradable and polymerized chitosan itaconate coating protects wood from fire • Inflammable chitosan itaconate films do not ignite or melt when exposed to fire • Polymerization significantly increases LOI and the thermal stability of the chitosan itaconate films. • Applied on wood the coating delays ignition and flame spread • Single application cuts burn rate by a third and with multiple layers the materials become self-extinguishing.
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