Mechanically Resilient, Self-Healing, and Environmentally Adaptable Eutectogel-Based Triboelectric Nanogenerators for All-Weather Energy Harvesting and Human–Machine Interaction

Triboelectric nanogenerators (TENGs) have garnered significant attention for mechanical energy harvesting, self-powered sensing, and human-machine interaction. However, their performance is often constrained by materials that lack sufficient mechanical robustness, self-healing capability, and adaptability to environmental extremes. Eutectogels, with their inherent ionic conductivity, thermal stability, and sustainability, offer an appealing alternative as flexible TENG electrodes, yet they typically suffer from weak damage endurance and insufficient self-healing capability. To overcome these challenges, here, we introduce an internal-external dual reinforcement strategy (IEDRS) that enhances internal bonding dynamics within the eutectogel matrix, composed of glycidyl methacrylate and deep eutectic solvent, and integrates plant-derived lignin as an external reinforcer. Notably, the resultant eutectogel, named GLCL, exhibits appealing collection merits including superior mechanical robustness (1.53 MPa tensile stress and 1.85 MJ/m