化学
轨道轨道
黄曲霉毒素
水溶液
激进的
声化学
降级(电信)
质谱法
内酯
呋喃
碎片(计算)
人体净化
色谱法
有机化学
食品科学
计算机科学
核物理学
物理
操作系统
电信
作者
Yuanfang Liu,Mengmeng Li,Ke Bian
出处
期刊:Toxins
[MDPI AG]
日期:2019-09-12
卷期号:11 (9): 526-526
被引量:31
标识
DOI:10.3390/toxins11090526
摘要
Ultrasound is an emerging decontamination technology with potential use in the global food processing industry. In the present study, we explored power ultrasound for processing aqueous aflatoxin B1 (AFB1). AFB1 was degraded by 85.1% after 80 min of ultrasound exposure. The reaction products of AFB1 were identified and their molecular formulae elucidated by ultra-high-performance liquid chromatography Q-Orbitrap mass spectrometry. Eight main reaction products were found, and their structures were clarified by parental ion fragmentation. Two degradation pathways were proposed according to the degradation product structures: One involved the addition of H• and OH• radicals, whereas the other involved H2O2 epoxidation and H•, OH•, and H2O2 oxidation of AFB1. Ultrasound treatment significantly reduced AFB1 bioactivity and toxicity by disrupting the C8=C9 double bond in the furan ring and modifying the lactone ring and methoxy group.
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