阳离子聚合
化学
选择性
肽
电渗析
超滤(肾)
色谱法
膜
氨基酸
生物化学
有机化学
催化作用
作者
V.Y. Koumfieg Noudou,Shyam Suwal,Jean Amiot,Sergey Mikhaylin,Lucie Beaulieu,Laurent Bazinet
标识
DOI:10.1016/j.seppur.2015.11.020
摘要
The present work aimed to determine the effect of initial peptide concentration (0.5%, 1%, 2% and 4% (w/v) in feed solution during electrodialysis with ultrafiltration membranes (EDUF) on migration rate and selectivity of both anionic and cationic peptides as well as on electrodialytic parameters. The results showed that increasing the peptide concentration in the feed solution from 0.5% to 4% increased, in a linear way, the total separation rate and affected the selectivity of free amino acids in both recovery compartments RCA− (Asp, Glu and His) and RCC+ (Arg mainly) and/or peptides containing these amino acids. The highest migration rates observed at 4% were 16.2 g/m2 h and 7.8 g/m2 h for the cationic and anionic compartments respectively. Furthermore, the relative energy consumption decreased with increasing feed solution concentration from 17.4 Wh/g at 0.5% concentration to 3.53 Wh/g at 4% concentration. In addition, membrane integrity and physicochemical properties were not affected in the range of peptide concentration tested. To the best of our knowledge, it was the first time that the impact of feed peptide concentration on migration, selectivity and relative energy consumption is demonstrated in EDUF.
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