电容去离子
石墨烯
三聚氰胺
制作
电极
材料科学
膜
纳米技术
聚合物
离子交换
三聚氰胺树脂
离子
化学工程
纳米孔
石墨烯泡沫
电化学
氧化石墨烯纸
化学
复合材料
有机化学
病理
物理化学
工程类
替代医学
医学
生物化学
涂层
作者
Sheng Zhang,Yonghong Deng,Chaoyang Wang
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2017-01-03
卷期号:5 (1): 325-333
被引量:33
标识
DOI:10.1021/acssuschemeng.6b01685
摘要
A novel nitrogen-doped reduced graphene sponge composite (NRGS) is fabricated by using melamine sponge to restrain the aggregation of graphene sheets during reduction. The anion-exchange polymer layered graphene composites (A-NRGS) are prepared by coating the surface of the NRGS electrode with cross-linked poly(vinyl alcohol) with quaternization modification (C-qPVA). With the help of a melamine sponge to suppress the agglomerate of graphene sheets, the NRGS exhibits a unique three-dimensional (3D) interconnected porous structure with abundant nitrogen doping of 5.2%. Its specific surface area is up to 241 m2/g. In addition, the enhanced wettability of A-NRGS composites favors the diffusion of ion from the electrolyte to electrode. Therefore, A-NRGS composites have excellent electrochemical capacity (184 F/g). The membrane capacitive deionization (MCDI) performance for A-NRGS electrode (11.3 mg/g) is higher than that of pristine reduced graphene oxide (RGO) (6.2 mg/g) and NRGS (8.6 mg/g) electrodes. All t...
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