荧光粉
分析化学(期刊)
材料科学
光谱学
化学
光电子学
物理
色谱法
量子力学
作者
Ikhlas Kachou,Kamel S. Saidi,Rached Salhi,M. Dammak
出处
期刊:RSC Advances
[The Royal Society of Chemistry]
日期:2022-01-01
卷期号:12 (12): 7529-7539
被引量:19
摘要
A new Na3Y(VO4)2:Eu3+ (NYVO:Eu3+) phosphor was prepared using the sol-gel method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to evaluate phase purity and particle size, respectively. The optical properties were investigated by UV-visible absorption, PL, and PLE spectroscopies. The absorption measurements show the formation of the vanadate host by the presence of its characteristic band in the visible region related to VO43- groups. The experimental results show that the NYVO:Eu3+ phosphors exhibit high-brightness and thermally stable emission. Under near-ultraviolet (UV) excitation, both the broadband emission from VO43- groups and the sharp peak emissions from Eu3+ ions are observed. The highest luminescence intensity was achieved for an optimal europium concentration of 15 mol%. The study of the chromaticity parameters of these compounds gives a thermally stable hot emission in the red domain, with a color purity of about 85%, which qualifies the NYVO:Eu3+ compound as a potential phosphor for light-emitting diode (LED) applications. Thermal sensing using NYVO:Eu3+ phosphors are based on monitoring the luminescence intensity ratio between the NYVO host emission and Eu3+ luminescence lines. Notably, the optical thermometry of NYVO:Eu3+ was characterized based on the fluorescence intensity ratio of VO43- and Eu3+ emissions in the 298-440 K range, with maximum absolute and relative sensitivities of 3.4% K-1 and 0.0032 K-1 respectively and a temperature uncertainty of 0.01. NYVO:Eu3+ can then be considered as a potential red phosphor for application in ultraviolet-pumped white light-emitting diodes and as a potential optical thermometer. It provides new possibilities for the design of multifunctional materials for red light-emitting diodes and for non-contact thermometry.
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