Surface Oxygen Vacancies and Carbon Dopant Co-Decorated Magnetic Znfe2o4 as Photo-Fenton Catalyst Towards Efficient Degradation of Tetracycline Hydrochloride

Carbon doped strategy has been recognized as an efficient strategy to enhance photo-Fenton degradation performance. However, the preparation of high efficiency C-doped photocatalyst has been a significant challenge. Herein, we synthesized magnetic carbon-doped ZnFe2O4 via a facile solvothermal-calcination route. The photo-Fenton activity of C-doped ZnFe2O4 under visible light (λ > 420 nm) was evaluated by degradation of tetracycline hydrochloride. C-doped sample, CZF-2 (0.5 g L-1) presented excellent removal performance for TC-HCl (20 mg L-1) in presence of H2O2 (10 mM) and could remove 90.8% of TC-HCl within 50 min. The C-doping modulates crystal defects and generates surface oxygen vacancies simultaneously, thus building a new C-doping level near valence band and a defect level under the conduction band. Meanwhile, surface oxygen vacancies bring photo-generated electrons and electrons generated from itself to surface to accelerate photo-Fenton reaction, and the holes are rapidly transferred to the surface to participate in the degradation of pollutants.