Rubber-like Deep Eutectic Solvent-Assisted Poly(N-acryloylglycinamide) Hydrogel for Highly Sensitive Pressure Detecting

Deep eutectic solvent (DES)-based conductive hydrogels have attracted great interest in the building of flexible electronic devices that can be used to replace conventional temperature-intolerant hydrogels and expensive ionic liquid gels. However, current DES-based conductive hydrogels obtained have limited mechanical strength, high hysteresis, and poor microdeformation sensitivity of the assembled sensors. In this work, a rubber-like conductive hydrogel based on N-acryloylglycinamide (NAGA) and DES (acetylcholine chloride/acrylamide) has been synthesized by a one-step method. The prepared conductive PNAGA-DES hydrogel has exhibited excellent mechanical strength, stability, and resilience during the long-term loading-unloading cycles, endowed with service durability. Besides, the as-prepared PNAGA-DES also possesses high transparency, high conductivity, and favorable antienvironmental disturbance, which can enhance the designability and robustness of the PNAGA-DES-based devices. Based on the remarkable properties, the PNAGA-DES hydrogel can be used for wearable pressure-strain sensors with high sensitivity of tiny strain for transferring information (gauge factor (GF) = 8.18, 0.2-2% strain) and long-term stability. Furthermore, it can also sensitively detect the large strain of human motion, showing potential application in information interaction and wearable electronics.