Unexpected shifts of dissolved carbon biogeochemistry caused by anthropogenic disturbances in karst rivers

Dissolved carbon (C) provides critical feedbacks to regional biogeochemical processes and global C cycling. Yet to date, the specific pathways of fluvial dissolved C turnover, particularly with human-induced shifts involved, are still poorly understood. Here, we examined dissolved inorganic (DIC) and organic C (DOC), as well as human disturbances i.e., river damming and land use in karst rivers. We show that anthropogenic activities caused unexpected shifts to dissolved C biogeochemistry. Specifically, we found that human disturbances accelerated aquatic metabolism, ultimately causing more river CO