阳极
碳化
材料科学
微型多孔材料
碳纤维
锂(药物)
化学工程
煤
水热碳化
多孔性
电化学
氢氧化钾
纳米技术
化学
复合材料
电极
扫描电子显微镜
有机化学
工程类
内分泌学
复合数
物理化学
医学
作者
Ziyu Chen,Anni Zhang,Chao Geng,Jianzhen Xiong,Pengchang Sun,Ni Tu,Yaxin Chen,Jiangmin Jiang,Zhicheng Ju
标识
DOI:10.1016/j.matchemphys.2023.127835
摘要
Carbon-based materials exhibit the advantages of low-operating voltages and non-toxicity and are thus considered promising anode components for potassium-ion batteries (PIBs) and lithium-ion batteries (LIBs). Herein, hydrothermal treatment and KOH activation combined with high-temperature carbonization were employed to fabricate hierarchical porous carbon, in which the low-cost coal as the carbon source. The proposed material shows rich microporous structures that facilitate Li+/K+ adsorption/desorption and promote capacitive contributions, thus improving the dynamics of the electrochemical reaction. CBC-700 (carbonized at 700 °C), as an LIB anode material, delivers a specific capacity of up to 844 mAh g−1, maintains 597 mAh g−1 under 1000 mA g−1 current density, and exhibits excellent capacity reversibility. When applied as a PIB anode material, the reversible specific capacity is preferable, with a value of 314 mAh g−1, and the specific capacity at 500 mA g−1 is 235 mAh g−1, apart from exhibiting excellent capacity reversibility. Significantly, it is highly expected that the coal-based carbon shows potential as an anode for the large-scale production of highly efficient LIBs and PIBs.
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