3D printed epoxy/acrylate hybrid polymers with excellent mechanical and shape memory properties via UV and thermal cationic dual-curing mechanism

Fabricating shape memory polymers with complex configurations and high mechanical performance for application as structural materials remains a significant challenge. Here, an epoxy/acrylate hybrid material with remarkable mechanical properties and excellent shape memory performance is fabricated using vat photopolymerization printing technology through photo-thermal dual curing mechanism. The UV-curing component comprises of a polyurethane acrylate and a rigid active diluent to ensure robustness and toughness. Meanwhile, the thermal curing epoxy constituent utilizes a benzylanilinium salt as the cationic initiator for its storage and handling stability throughout the UV curing stage. The interpenetrating polymer network and the unique two-phase molecular microstructure impart the hybrid material with good shape memory and high mechanical properties. Many complex objects are fabricated using vat photopolymerization printing technology and employed in self-deploying antennas, intelligent mechanical grippers, and switches. Combining with excellent printability, mechanical and shape memory properties, the hybrid materials have great potential applications in various fields.