Concentrations and distributions of fluorotelomer alcohols and perfluoroalkane sulfonamido substances in the atmosphere in the Pearl River Delta, China

AbstractPer and polyfluoroalkyl substances (PFASs) have attracted major global concerns because some of them are environmentally persistent, bioaccumulative, and toxic. Perfluoroalkyl acids (PFAAs) have been well-characterized in water, soil, and sediment; however, fluorotelomer alcohols and perfluoroalkane sulfonamido substances have been overlooked. In this study, concentrations of three fluorotelomer alcohols and four perfluoroalkane sulfonamido substances were determined in the air at nine locations representing urban, rural-urban transect, and urban areas in the Pearl River Delta region, China to investigate their seasonal and spatial distributions and potential sources. At least two of the targeted PFASs were detected in all air samples in the Pearl River Delta region, with concentrations ranging from 371 pg/sampler to 18700 pg/sampler. Fluorotelomer alcohols were dominant compounds (contributing 46% to the ∑7PFAS concentration on average) in the atmosphere in the Pearl River Delta region. The total concentrations of the seven targeted PFASs were significantly higher in summer than in other seasons in urban areas. PFAS concentrations were positively related to the population density in the Pearl River Delta region. Local diffusive emission and long range transport could be sources of the seven PFASs in the air in the Pearl River Delta region.Keywords: PFASs in the airpotential sourcesand seasonal variation Declaration of interest statementThere is no competing interest.Data availability statementThe authors confirm that the data supporting the findings of this study are available within the article [and/or] its supplementary materials.Additional informationFundingThis study was supported by the National Key Research and Development Program of China (2021YFC1809104).