CsBr-Triggered Reversible Phase Transition of Perovskite Nanocrystals for Advanced Information Encryption and Decryption

Luminescent perovskite nanocrystals (NCs), possessing the advantages of low cost, easy detection, and excellent luminescence, are becoming more and more significant in the fields of information encryption and decryption. Most hydrochromic perovskite NCs for information encryption have moderate reversibility and are easily passively decrypted by water in the moist air, limiting their practical applications. Herein, a lyochromic material is synthesized based on reversible phase transition between luminescent CsPbBr₃-HBr (pretreating CsPbBr₃ with HBr) and nonluminescent Cs₄PbBr₆, exhibiting excellent reversibility in 50 cycles triggered by CsBr solution. HBr treatment boosts the ion migration of NCs via diminishing surface ligands and passivating Br vacancy, assisting CsBr concentration acting as a crucial factor in dynamic ion exchange equilibrium between the trigger solution and CsPbBr₃-HBr. By utilizing CsPbBr₃-HBr as a safety ink, the CsBr-triggered photoluminescence switch has been demonstrated to be reproducible, stable, and reliable for information encryption and decryption.