High Performance Tandem Solar Cells with Inorganic Perovskite and Organic Conjugated Molecules to Realize Complementary Absorption

All-inorganic halide perovskite solar cells (PerSCs) have achieved rapid development in recent years. However, limited by narrow absorption bands, the power conversion efficiency (PCE) of all-inorganic halide PerSCs lag behind the organic–inorganic hybrid ones. In this contribution, to expand their absorption spectra and enhance the PCE, tandem solar cells (TSCs) with inorganic perovskite and organic conjugated molecules are constructed, utilizing CsPbI2Br as an ultraviolet–visible light absorber and a PTB7-Th:IEICO-4F bulk-heterojunction (BHJ) active layer as a near-infrared light absorber. To physically and electronically connect the front and rear subcells, P3HT/MoO3/Ag/PFN-Br is introduced as an interconnecting junction. Finally, the TSCs exhibit a remarkably higher PCE of 17.24% compared to that of the single junction PerSCs (12.09%) and organic solar cells (OSCs) (10.89%). These results indicate that the combination of all-inorganic perovskite and a low bandgap organic active layer for TSCs is a feasible approach to realize broad spectra utilization and efficiency enhancement.