材料科学
光催化
三聚氰胺
三聚氰酸
石墨氮化碳
水溶液
分解水
乙二醇
化学工程
碳纤维
氮化碳
纳米片
纳米技术
光化学
有机化学
催化作用
复合材料
化学
工程类
复合数
作者
Lingfeng Li,Juhua Zhang,Quan Zhang,Xiaohao Wang,Wei‐Lin Dai
出处
期刊:Nanotechnology
[IOP Publishing]
日期:2021-01-25
卷期号:32 (15): 155604-155604
被引量:15
标识
DOI:10.1088/1361-6528/abd6d1
摘要
The photocatalytic evolution of hydrogen (H2) from water splitting is considered a promising route to overcome the energy crisis, and the key lies in the preparation of efficient photocatalysts. Herein, superior ordered sponge-like carbon self-doped graphitic carbon nitride (g-C3N4) nanosheets (SCCNS) were prepared via a combined strategy of melamine-cyanuric acid complex supramolecular pre-assembly and solvothermal pre-treatment using ethylene glycol (EG) aqueous solutions (EG:water = 50:50 vol.%) as a solvent and carbon doping source. The following pyrolysis converts the naturally arranged melamine-EG-cyanuric acid supramolecular intermediates to highly crystalline SCCNS with large specific surface areas. The optimal SCCNS-180 exhibits superior photocatalytic H2 evolution activities (∼4393 and 11 320 μmol h-1 g-1) when irradiated with visible light and simulated sunlight; these values are up to ∼17- and ∼18-fold higher than that of bulk g-C3N4. The quantum efficiency of SCCNS-180 at λ = 420 nm can reach 6.0%. The excellent photocatalytic performance of SCCNS-180 derives from its distinct ordered sponge-like nanosheet structure with highly crystallinity and the carbon doping, leading to its improved optical absorption, accelerated photoinduced electron-hole pair transfer and separation rate and enlarged specific surface area (134.4 m2 g-1).
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