Dissolved organic matter (DOM) removal from biotreated coking wastewater by chitosan-modified biochar: Adsorption fractions and mechanisms

To effectively remove dissolved organic matter (DOM) from actual biotreated coking wastewater (BTCW), a reusable and low-cost chitosan-biochar (CB) was prepared. From the results, CB (52%) exhibited superior removal efficiency compared to that of biochar (12%) and a faster adsorption rate. Analysis of the DOM fractions, molecular weight distribution, fluorescent components, and molecular compositions indicated that chitosan modification made more kinds of DOM components (e.g., hydrophilic substances) have an affinity with biochar. The material characterization and removal characteristics jointly proved that the adsorption efficiency was promoted by the change in pore size distribution and increase in functional groups that provide bonding sites for DOM via hydrogen bonding, acid-base reactions, and electrostatic interactions. Moreover, compared to traditional adsorbent activated carbon, CB exhibited superior removal efficiency and cost-effectiveness. These results demonstrated that CB is a potential alternative adsorbent for advanced DOM treatment of BTCW.