Conjugated Carbonyl Polymer-Based Flexible Cathode for Superior Lithium-Organic Batteries

Conjugated carbonyl compounds are deemed as high theoretical capacity and green electrode materials for lithium-ion batteries (LIBs) but are limited by their high dissolution and poor electronic conductivity. In this paper, we have successfully synthesized a series of multicarbonyl conjugated polymers using the coupling polymerization reaction and then constructed carbonyl-conjugated polymer/carbon nanotube hybrid films by a vacuum-filtration method. Importantly, the hybrid films could serve as a flexible, binder-free, and free-standing organic cathode for LIBs, which could deliver a high reversible discharge capacity of 142.3 mAh g–1 at 50 mA g–1, good cycling stability with a capacity retention of 74.6% at 500 mA g–1 after 300 cycles, and excellent rate capability of 120.6 mAh g–1 at 1000 mA g–1. In addition, the theoretical calculation has proved that the symmetrical conjugated structure can well accommodate four Li+ ions during the electrochemical reaction. Interestingly, the assembled full cell and flexible battery can power the small devices, suggesting its potential to use in bendable or wearable energy-storages devices.