材料科学
离子电导率
陶瓷
纳米纤维
电解质
快离子导体
锂(药物)
电导率
离子键合
法拉第效率
制作
电池(电)
复合材料
化学工程
纳米技术
离子
电极
物理化学
有机化学
病理
量子力学
功率(物理)
医学
化学
物理
替代医学
内分泌学
工程类
作者
Yun Zhao,Jianhua Yan,Weiping Cai,Yimei Lai,Jun Song,Jianyong Yu,Bin Ding
标识
DOI:10.1016/j.ensm.2019.04.043
摘要
Ceramic Li7La3Zr2O12 is one of the most attractive electrolyte materials for solid-state batteries due to its high ionic conductivity and chemical/thermal stability, but the battery performance is always limited by the high electrolyte-electrode interfacial resistances. Here, we have fabricated elastic solid electrolytes by filling ionic-conductive polymers into well-aligned Li6.4La3Zr2Al0.2O12 (LLZO) nanofiber films. Such electrolytes can provide fast and continuous ionic-transportation channels and thus exhibit a high ionic conductivity of 1.16 × 10−4 S cm−1 at 30 °C. Moreover, the elastic surfaces of the electrolytes can well conform to electrodes without separations to adapt volume changes of the electrodes during the repeated cycles, enabling a stable Li plating/stripping cycling over 700 h. Fabricated solid-state NCA//Li cells exhibit ultra-low internal resistances of 87 Ω and deliver large discharge capacities with high Coulombic efficiencies that are comparable with the liquid type batteries. The reported approach allows low-cost fabrication of solid electrolytes that possess high ionic conductivity for solid state batteries.
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