Windmill-shaped octanuclear ZnII4/LnIII4 (LnIII = Dy, Tb, Ho) heterometallic ensembles supported by a tetraferrocene scaffold

Utilizing a new ferrocene-based compartmental ligand, H₄L (1), a series of novel heterometallic complexes [{LZn(μ-OAc)Dy}₄(μ₄-H₂O)] (2), [{LZn(μ-OAc)Tb}₄(μ₄-H₂O)] (3), [{LZn(μ-OAc)Ho}₄(μ₄-H₂O)] (4), [L = Fe[(C₅H₄){–C(Me)N–NC₆H₃-(o-O)(m-O)}]₂] were synthesized and characterized.