纳米晶材料
结晶度
材料科学
电化学
锂(药物)
锂离子电池
结构精修
化学工程
阴极
混合(物理)
降水
电池(电)
晶体结构
纳米技术
复合材料
结晶学
化学
电极
物理化学
热力学
医学
功率(物理)
物理
内分泌学
量子力学
气象学
工程类
作者
Lingjun Li,Xinhai Li,Zhixing Wang,Huajun Guo,Yue Peng,Wei Chen,Ling Wu
标识
DOI:10.1016/j.powtec.2010.09.010
摘要
Nanocrystalline materials of Ni0.8Co0.1Mn0.1(OH)2 are successfully synthesized by fast co-precipitation method. The crystalline structure and morphology of the precursors and LiNi0.8Co0.1Mn0.1O2 materials are characterized by XRD, SEM and Rietveld refinement analyses. It is found that the nanocrystalline phase and low crystallinity of Ni0.8Co0.1Mn0.1(OH)2 could help achieve its uniform mixing with lithium source, and further attribute to highly ordered layered LiNi0.8Co0.1Mn0.1O2 with low cation mixing degree. Electrochemical studies confirm that the LiNi0.8Co0.1Mn0.1O2 exhibits a good electrochemical property with initial discharge specific capacity of 192.4 mAh g− 1 at a current density of 18 mA g− 1, and the capacity retention after 40 cycles is 91.56%. This method is a simple and effective method to synthesize cathode material.
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