微生物燃料电池
催化作用
限制电流
碳化
碳纤维
化学
阴极
化学工程
磷
小虾
氮气
核化学
材料科学
无机化学
阳极
吸附
电化学
电极
有机化学
复合材料
物理化学
工程类
复合数
渔业
生物
作者
Fengyi Zheng,Ruisong Li,Shiyu Ge,Wen-Rong Xu,Yucang Zhang
标识
DOI:10.1016/j.jpowsour.2019.227356
摘要
The waste shrimp shells (SS) were used as both carbon and nitrogen sources to directly synthesize N and P co-doped carbon networks with abundant mesopores and high specific surface area by simple acid pretreatment and carbonization. Using exogenous phosphorus as dopant, the prepared catalyst (PA-SS 900) favorably possessed a high oxygen reduction reaction (ORR) activity regarding half-wave potential (0.82 V) and limiting current (4.47 mA cm−2), which approached those of commercial 20 wt% Pt/C. For practical application in microbial fuel cell (MFC), the N, P co-doped PA-SS 900 achieved a maximum power density (MPD) of 802 mW m−2 and an open circuit voltage (OCV) of 653 mV, which also were close to that (892 mW m−2 and 752 mV) based on 20% Pt/C as cathode catalyst. Remarkably, the synthetic catalyst had a better long-term stability than that of 20% Pt/C in alkaline medium. These results demonstrated that N, P co-doped PA-SS 900 was an accessible and efficient ORR catalyst in air-cathode MFC for relatively desirable energy generation and wastewater treatment. Further, the direct utilization of waste shrimp shells replacing chitin or chitosan in energy conversion is worthy of in-depth study due to the advantages of simple process, environmental friendliness and availability.
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