非阻塞I/O
光催化
材料科学
异质结
制氢
分解水
化学工程
可见光谱
纳米技术
光催化分解水
纳米颗粒
氢
光电子学
催化作用
化学
工程类
有机化学
生物化学
作者
Chonghai Deng,Fan Ye,Tao Wang,Xuemei Ling,Lulu Peng,Hong Yu,Kangzhe Ding,Hanmei Hu,Qiang Dong,Huirong Le,Yongsheng Han
出处
期刊:Nano Research
[Springer Nature]
日期:2021-11-23
卷期号:15 (3): 2003-2012
被引量:44
标识
DOI:10.1007/s12274-021-3960-4
摘要
The hierarchical binary CdS/NiO hollow heterogeneous architectures (HHAs) with p-n heterojunction are constructed by a facile microwave-assisted wet chemical process for high-efficient photocatalytic hydrogen evolution reaction (HER) from water. The asdesigned CdS/NiO HHAs are composed of hexagonal n-type CdS nanoparticles with a size in the range of 20–40 nm attaching to cubic p-type NiO hollow microspheres (HMSs) which are aggregates of porous nanoplates with a thickness of about 20 nm. The photocatalytic water splitting over CdS/NiO HHAs is significantly increased under simulated solar irradiation, among which the most active sample of CdS/NiO-3 (the mass ratio of CdS to NiO is 1:3) exhibits the fastest photocatalytic HER rate of 1.77 mmol·g−1·h−1, being 16.2 times than that of pure CdS. The boosted photocatalytic HER could be attributed to the synergistic effect on the proportional p-n heterojunction with special hierarchical hollow and porous morphology, an enhancement of visible light absorption, and an improvement of photoinduced charge separation as well as the photo-stability given by the composite heterojunction. This work shows a viable strategy to design the heterojunction with special morphology for the efficient hydrogen generation by water splitting utilizing solar energy.
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