渗透
膜
共价键
材料科学
纳米技术
经济短缺
表面电荷
化学工程
选择性
共价有机骨架
电荷(物理)
化学
有机化学
物理化学
催化作用
政府(语言学)
哲学
工程类
物理
量子力学
生物化学
语言学
作者
Weiwen Xin,Yongchao Qian,Bo Niu,Weipeng Chen,Congcong Zhu,Xiangyu Kong,Lei Jiang,Liping Wen
标识
DOI:10.1016/j.mattod.2021.10.021
摘要
Molecular separation is critical to mitigating the issues of water contamination and shortage and currently focuses on the use of framework materials fabricated by special building blocks. However, developing a simple and tunable synthesis methodology for materials with alternative permeation and selectivity remains challenging. Here, we fabricate a series of nanochannel membranes composed of uniform spherical covalent organic frameworks (COFs). Diversified spherical COFs have diameters ranging from ∼150 to ∼800 nm, therefore demonstrating a programmable surface charge distribution from −24 to −63 mV. COF membranes with tailor-made surface charge enable different surface energy levels and allow increasing water permeation of 15.5 to 34.5 L m−2 h−1 bar−1. Furthermore, COFs can also act as filters, achieving up to 99.7% rejection and separation of the opposite charged dyes. We expect these COFs with tunable surface charge to be applicable to variety of fields, including sieving, batteries, and water treatments.
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