化学
检出限
抗坏血酸
六价铬
铬
荧光
线性范围
碳纤维
核化学
猝灭(荧光)
分析化学(期刊)
无机化学
色谱法
有机化学
物理
复合材料
复合数
材料科学
量子力学
食品科学
作者
Yuhua Zhang,Xian Fang,Hong Zhao,Zengxi Li
出处
期刊:Talanta
[Elsevier]
日期:2018-05-01
卷期号:181: 318-325
被引量:123
标识
DOI:10.1016/j.talanta.2018.01.027
摘要
A highly sensitive and selective detection of hexavalent chromium (Cr(VI)) and ascorbic acid (AA) was proposed using nitrogen-doped carbon dots (N-CDs). In the absence of AA, the quantitative detection of Cr(VI) was realized through Cr(VI) acting as a quencher to quench the fluorescence of N-CDs by inner filter effect (IFE) and static quenching effect. Under the optimal conditions, the linear range for Cr(VI) detection was from 0.01 to 250 μM with a detection limit of 5 nM (S/N = 3). In the presence of AA, the fluorescence intensity could be rapidly enhanced compared with the fluorescence of N-CDs/Cr(VI) system since Cr(VI) can be reduced into trivalent chromium (Cr(III)) by AA. And a wide linear range for AA detection was obtained from 1 to 750 μM. The detection limit was 0.3 μM (S/N = 3). More importantly, this method can be successfully applied to the detection of Cr(VI) in real water samples, and AA in vitamins C tablets and human serum sample.
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