试剂
氧化剂
计算机科学
生化工程
化学
可再生能源
工艺工程
纳米技术
电
有机化学
材料科学
工程类
电气工程
物理化学
作者
Anton Wiebe,Tile Gieshoff,Sabine Möhle,Eduardo Rodrigo,Michael Zirbes,Siegfried R. Waldvogel
标识
DOI:10.1002/anie.201711060
摘要
The direct synthetic organic use of electricity is currently experiencing a renaissance. More synthetically oriented laboratories working in this area are exploiting both novel and more traditional concepts, paving the way to broader applications of this niche technology. As only electrons serve as reagents, the generation of reagent waste is efficiently avoided. Moreover, stoichiometric reagents can be regenerated and allow a transformation to be conducted in an electrocatalytic fashion. However, the application of electroorganic transformations is more than minimizing the waste footprint, it rather gives rise to inherently safe processes, reduces the number of steps of many syntheses, allows for milder reaction conditions, provides alternative means to access desired structural entities, and creates intellectual property (IP) space. When the electricity originates from renewable resources, this surplus might be directly employed as a terminal oxidizing or reducing agent, providing an ultra-sustainable and therefore highly attractive technique. This Review surveys recent developments in electrochemical synthesis that will influence the future of this area.
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