纤维素
光催化
材料科学
化学工程
原位
水溶液
锌
纳米纤维素
细菌纤维素
羟丙基纤维素
堆积
催化作用
化学
有机化学
复合材料
聚合物
工程类
冶金
作者
Yichen Zhou,Ying Zhang,Lu Zhang,Jianhao Qiu,Jianfeng Yao
标识
DOI:10.1016/j.carbpol.2023.120845
摘要
The delicate design of photocatalyst monoliths is of great significance for the practical applications of artificial photocatalysis. An in-situ synthesis to prepare ZnIn2S4/cellulose foam was developed. Cellulose is dispersed in a highly concentrated ZnCl2 aqueous solution to prepare Zn2+/cellulose foam. Zn2+ ions are pre-anchored by hydrogen bonds on cellulose and become in-situ sites for synthesizing ultra-thin ZnIn2S4 nanosheets. This synthesis method makes ZnIn2S4 nanosheets and cellulose tightly bound and prevents ZnIn2S4 nanosheets from stacking in multiple layers. As a proof of concept, the prepared ZnIn2S4/cellulose foam exhibits a favorable performance for photocatalytic reduction of Cr(VI) under visible light. By adjusting the concentration of zinc ions, the optimal ZnIn2S4/cellulose foam is capable to completely reduce Cr(VI) in 2 h and the photocatalytic activities show no decrease after 4 cycles. This work could inspire people to build floating cellulose-based photocatalysts via in-situ synthesis.
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