MgCo layered double hydroxide-based yolk shell polyhedrons as multifunctional sulfur mediator for lithium–sulfur batteries

The development of efficient sulfur host materials to address the shuttle effect issues of lithium polysulfides (LiPSs) is crucial in the lithium-sulfur (Li-S) batteries but still challenging. In the present study, a novel yolk shell structured MgCo-LDH/ZIF-67 composite is designed as Li-S battery cathode. In this composite, the shell layer is MgCo layered double hydroxide constructed by partially etching ZIF-67 nanoparticle by Mg2+, and the core is the unreacted ZIF-67 particle. The unique yolk shell structure not only provides abundant pores for sulfur accommodation, but also facilitates the electrolyte penetration and ion transport. The ZIF-67 core exhibits strong polar adsorption to LiPSs through the Lewis acid-base interactions, and the micropores/mesoporous can further trap LiPSs. Meanwhile, the MgCo-LDH shell exposes enough sulfur-philic sites for enhancing chemisorption and catalyzes LiPSs conversion. As a result, when MgCo-LDH/ZIF-67 is used as sulfur host in the cathode, the cell achieves a high discharge capacity of 1121 mAh g-1at 0.2 C, and an areal capacity of 5.0 mAh cm-2under high sulfur loading of 5.8 mg cm-2. The S/MgCo-LDH/ZIF-67 electrode holds a promising potential for the development of Li-S batteries.