单斜晶系
吸附
正交晶系
催化作用
化学
三羧酸
联苯
金属有机骨架
选择性
结晶学
化学工程
无机化学
晶体结构
有机化学
工程类
柠檬酸循环
酶
作者
Xiuling Zhang,Yongzheng Zhang,Wenfeng Zhou,Huiling Liu,Da‐Shuai Zhang,Hui Hu,Chao Lv,Sui‐Jun Liu,Longlong Geng
标识
DOI:10.1016/j.cclet.2022.03.091
摘要
Synthetic conditions and ligands are the key structural defining factors of metal–organic frameworks (MOFs). Therefore, reasonable optimization of these aspects is considered to be an effective means for designing materials with novel structures and target functions. Herein, two novel Co(II)-based MOFs, namely [Co(HL)(dibp)]n (HL-8) and {[Co2(L)(OH)(dibp)]·DMA}n (HL-9) (H3L = 2′,6′-dimethyl-[1,1′-biphenyl]-3,4′,5-tricarboxylic acid; dibp = 4,4′-di(1H-imidazol-1-yl)-1,1′-biphenyl]), have been hydrothermally synthesized and structurally characterized. HL-8 crystallizes in the orthorhombic system (Pna21) with a grid layer structure, while HL-9 crystallizes in the monoclinic P21/n space group assembled through Co4(OH)2 clusters with organic ligands. Remarkably, benefiting from the finite cage-like structure, HL-9 exhibited enhanced performance in carbon dioxide (CO2) adsorption/catalytic transformation and excellent size selectivity during dye molecular adsorption process.
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