聚丙烯腈
吸附
选择性吸附
化学
胺化
纤维
化学工程
铜
吸收(声学)
氨
甲烷
丙烷
配体(生物化学)
天然气
无机化学
材料科学
聚合物
催化作用
有机化学
复合材料
工程类
生物化学
受体
作者
Zhihao Liu,Gang Sun,Zhijie Chen,Yue Ma,Kui Qiu,Min Li,Bing‐Jie Ni
标识
DOI:10.1016/j.jhazmat.2023.131084
摘要
As an essential part of clean energy, natural gas is often mixed with varying degrees of H2S and CO2, which poses a serious environmental hazard and reduces the fuel's calorific value. However, technology for selective H2S removal from CO2-containing gas streams is still not fully established. Herein, we synthesized functional polyacrylonitrile fibers with Cu-N coordination structure (PANFEDA-Cu) by an amination-ligand reaction. The results showed that PANFEDA-Cu exhibited a remarkable adsorption capacity (143 mg/g) for H2S at ambient temperature, even in the presence of water vapor, and showed a good separation of H2S/CO2. X-ray absorption spectroscopy results confirmed the Cu-N active sites in as-prepared PANFEDA-Cu and the formed S-Cu-N coordination structures after H2S adsorption. The active Cu-N sites on the fiber surface and the strong interaction between highly reactive Cu atoms and S are the main reasons for the selective removal of H2S. Additionally, a possible mechanism for the selective adsorption/removal of H2S is proposed based on experimental and characterization results. This work will pave the way for the design of highly efficient and low-cost materials for gas separation.
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