孔雀绿
共价键
化学
化学工程
环境化学
有机化学
吸附
工程类
作者
Shuaijie Zhang,Douchao Mei,Ké Li,Bing Yan
标识
DOI:10.1016/j.seppur.2024.127812
摘要
In this study, imine-based COF (TpPa-2COOH) with abundant carboxyl groups is constructed by 1,3,5-triisopropylchloroglucitol (Tp) and 2,5-diaminoterephthalic acid (Pa-2COOH) via "one-step" approach with solvent stability and resistance to acidity and alkalinity. TpPa-2COOH COF achieves highly efficient malachite green (MG) adsorption with a maximum adsorption of 296.56 mg·g−1 at pH = 5, and the adsorption capacity exceeds many reported adsorbents. Meanwhile, TpPa-2COOH COF shows outstanding adsorption performance to MG, such as 97.67 % removal rate in actual water environments, unique selective adsorption of MG in kinds of contaminants and good adsorption capacity in highly concentrated salt solutions. Additionally, TpPa-2COOH COF shows 78.4 % removal rate after six cyclic desorption-adsorption, demonstrating its excellent recyclability. Furthermore, the processes of monolayer adsorption and chemisorption are confirmed by the isotherms and kinetics of adsorption experiments. The adsorption mechanisms of π-π interaction, electrostatic attraction, hydrogen bonding and channel adsorption are further verified by XPS, EDX, Zeta potential and DFT calculations. This work hopes the synthesis and adsorption application of carboxylated COFs provide new ideas for developing novel adsorbents.
科研通智能强力驱动
Strongly Powered by AbleSci AI