Dual Influence of Size and Electric Field on Gold Nanoparticles: Insights into 2D Monolayer Assembly

Self-assembled gold nanoparticles (Au-NPs) possess distinctive properties that are highly desirable in diverse nanotechnological applications. This study meticulously explores the size-dependent behavior of Au-NPs under an electric field, specifically focusing on sizes ranging from 5 to 40 nm, and their subsequent assembly into 2D monolayers on an n-type silicon substrate. The primary objective is to refine the assembly process and augment the functional characteristics of the resultant nanostructures. Utilizing a multifaceted analytical approach encompassing X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDXS), atomic force microscopy (AFM), and COMSOL multiphysics simulation, this work yields comprehensive insights. Results reveal that the electric field and nanoparticle size critically influence assembly dynamics due to variations in surface energy and electrostatic interactions. Larger Au-NPs (20, 30, and 40 nm) experience enhanced dipolar interactions and more substantial polarizability, enabling more efficient alignment and organization under an applied electric field. This leads to the formation of structured, uniform monolayers with minimal vacancies and smoother surfaces. In contrast, smaller Au-NPs (5, 10, and 15 nm) exhibit lower polarizability, which hampers alignment and promotes clustering and voids. XRD analysis delineates notable disparities in peak intensities and positions: smaller Au-NPs exhibit diminished (111) peak intensities, indicative of uneven distribution and crystallinity, whereas larger particles manifest higher intensities and well-defined peaks across multiple crystallographic planes. SEM images portray diverse surface coverages with AFM corroborating that larger Au-NPs achieve uniform and continuous monolayers with minimal height variations. COMSOL simulations substantiate these findings by illustrating the efficient alignment and settling of larger Au-NPs under the electric field. This study bridges critical gaps in understanding how nanoparticle size modulates assembly dynamics and the resultant properties of 2D Au-NP monolayers, offering pivotal insights into engineering advanced nanostructured materials tailored to specific applications in electronics, coatings, photonics, and catalysis.