Swelling damage characteristics induced by CO2 adsorption in shale: Experimental and modeling approaches

Carbon dioxide (CO2) geological sequestration represents a critical technology in mitigating climate change. Shale reservoirs demonstrate a pronounced affinity for CO2, resulting in adsorption-induced swelling that significantly impacts permeability, mechanical strength, injection efficiency, and sequestration safety. For this, we tried to explore the key factors driving the swelling of shale upon CO2 injection and its subsequent impact on reservoir properties. Utilizing a self-developed high-temperature-pressure gas adsorption apparatus, we measured strain in Jurassic shale at 308 K under constant hydrostatic pressure with helium (He) at 1300 psi (1 psi = 6.895 kPa) and CO2 at 850 psi. Next, we investigated the influence of CO2 concentration on swelling protentional while maintaining constant pressure, uncovering the anisotropic deformation in relation to pressure. It shows that CO2 adsorption induces significant swelling in shale, following a Langmuir-type pressure relationship. Deformation is more pronounced perpendicular than that parallel to the bedding plane. At low pressure, vertical swelling is 2.28 times greater than the horizontal; while at high pressure, the vertical compression is 31.26 times greater than the horizontal. It seems that the anisotropic swelling enhances permeability predictions during CO2 injection. Mixed gases under constant compression can prompt gas desorption, stress redistribution, and alterations in pore structure, amplifying He compression effect. The strain induced after replacing CO2 with He exceeds that from pure He injection. The asynchronous response of CO2-induced swelling and mechanical compression can precipitate crack propagation and fracturing. Overall, anisotropic swelling from CO2 adsorption changes pore structure and permeability, affecting fluid flow and storage. Considering CO2 concentration and anisotropic characteristics in reservoir modeling is essential for optimizing injection strategies and enhancing reservoir efficiency.