小学(天文学)
催化作用
酒精氧化
铜
化学
有机化学
组合化学
物理
天文
作者
Yibo Yu,Di Zhai,Zhengnan Zhengnan Zhou,Sheng Jiang,Hui Qian,Shengming Ma
摘要
Here, the first copper-catalyzed aerobic oxidation of primary alcohols to carboxylic acids with TEMPO and KHSO4 as the co-catalysts has been developed. The reaction exhibits excellent substrate scope and functional group compatibility under mild conditions. Even the very sensitive chiral alcohols, chiral amino alcohols, and alcohol-containing steroid skeletons may be oxidized to afford the corresponding carboxylic acids or lactones without racemization.
科研通智能强力驱动
Strongly Powered by AbleSci AI