A kinetic study on oxygen redox reaction of a double-perovskite reversible oxygen electrode—Part I: Experimental analysis

Abstract The carbon-free energy transition requires the spread of advanced technologies based on high-performing materials. In this framework and particularly referring to electrochemical energy converting systems, double perovskites are arousing more and more interest as mixed ionic electronic conductors with flexible manufacturing, appropriate tailoring for many tasks and high chemical stability. Among their possible applications, they form excellent oxygen electrodes in solid oxide cell technology used as fuel cells, steam/CO 2 electrolysis cells and electrochemical air separation units. In view of the encouraging results shown by SmBa 1− x Ca x Co 2 O 5+ δ co-doped double perovskite, this research work aims at a detailed analysis of SmBa 0.8 Ca 0.2 Co 2 O 5+ δ performance and the identification of kinetic paths for oxygen reduction and oxidation reactions. The electrochemical characterization was performed over a wide range of operation conditions to evaluate the electrode reversible behaviour and the interplay of the recognized phenomena governing the overall electrode kinetics.