层状双氢氧化物
过电位
材料科学
双金属片
析氧
塔菲尔方程
共沉淀
化学工程
氢氧化物
电化学
电解质
纳米技术
电极
化学
冶金
金属
工程类
物理化学
作者
Biying Liu,Man Zhang,Yuchen Wang,Zuo Chen,Kai Yan
标识
DOI:10.1016/j.jallcom.2020.156949
摘要
Layered double hydroxides (LDHs) containing transition metals with unsaturated d-bands are ideal candidates for oxygen evolution reaction (OER). However, the bulk layers and congested interlayers block the active sites and avoid the electrolyte access to the internal space. In this work, we report a simple coprecipitation coupled with the hydrothermal method for the direct growth of bimetallic NiCo-LDHs (5.01 nm), NiMn-LDHs (3.45 nm) and trimetallic NiCoMn-LDHs nanosheets (1.26 nm) on Ni foam and these fabricated electrodes exhibit the superior performance for OER. Notably, the NiCoMn-LDHs nanosheets exhibit the lowest overpotential of 290 mV at 20 mA cm−2 and the smallest Tafel slope of 87 mV dec−1, reducing by 20–40 mV and 31–39 mV dec−1 in comparison with those of bimetallic NiCo-LDHs (310 mV, 118 mV dec−1) and NiMn-LDHs (330 mV, 126 mV dec−1). This excellent performance is attributed to the 2D structure of the nanosheets and an abundance of exposed active sites, especially oxygen vacancies. Additionally, NiCoMn-LDHs nanosheets exhibit the smallest charge transfer resistance (Rct) of 6.3 Ω and the largest electrochemical double layer capacitance (Cdl) of 5.52 mF cm−2 than those of the bimetallic NiCo-LDHs (11.0 Ω, 4.85 mF cm−2) and NiMn-LDHs (30.6 Ω, 3.00 mF cm−2). Furthermore, NiCoMn-LDHs nanosheets maintain good durability over 10 h and cyclic stability without distinct change. This work offers a facile strategy to design various types of bimetallic and trimetallic LDHs boosting for OER process.
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