电池(电)
阴极
阳极
电解质
材料科学
水溶液
化学工程
聚合物
氧化还原
聚合
电极
化学
无机化学
复合材料
有机化学
量子力学
物理
工程类
物理化学
功率(物理)
作者
Christian Strietzel,Mia Sterby,Hao Huang,Maria Strömme,Rikard Emanuelsson,Martin Sjödin
标识
DOI:10.1002/anie.202001191
摘要
Abstract Electrodes based on organic matter operating in aqueous electrolytes enable new approaches and technologies for assembling and utilizing batteries that are difficult to achieve with traditional electrode materials. Here, we report how thiophene‐based trimeric structures with naphthoquinone or hydroquinone redox‐active pendent groups can be processed in solution, deposited, dried and subsequently polymerized in solid state to form conductive (redox) polymer layers without any additives. Such post‐deposition polymerization offers efficient use of material, high mass loading (up to 10 mg cm −2 ) and good flexibility in the choice of substrate and coating method. By employing these materials as anode and cathode in an acidic aqueous electrolyte a rocking‐chair proton battery is built. The battery shows good cycling stability (85 % after 500 cycles), withstands rapid charging, with full capacity (60 mAh g −1 ) reached within 100 seconds, allows for direct integration with photovoltaics, and retains its favorable characteristics even at −24 °C.
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