罗丹明B
纳米颗粒
光催化
化学工程
吸附
催化作用
化学
降级(电信)
材料科学
比表面积
纳米技术
有机化学
计算机科学
电信
工程类
作者
Meiwen Cao,Ziwei Zhuang,Liu Yang,Zijin Zhang,Jiaming Xuan,Qinghua Zhang,Wentao Wang
标识
DOI:10.1016/j.jcis.2021.11.003
摘要
The MnO2@ZIF-8 core-shell nanoparticles for highly efficient dye degradation have been synthesized with a green method. ZIF-8 crystals with controlled morphology and size are first synthesized by using peptide to modulate the crystal growth. MnO2 is then coated on ZIF-8 via in situ reaction. The surface MnO2 density can be controlled by the dosage of KMnO4. The MnO2@ZIF-8 nanoparticles work as photocatalyst to degrade rhodamine B in a Fenton-like process, giving a degradation ratio of > 96.0%. The degradation kinetics comply well with the Pseudo-second-order model and the experimental equilibrium data meet the Langmuir model best. The specific hierarchical structure of MnO2@ZIF-8 assures a synergistic enhancement of the catalytic degradation performance from several aspects. First, anchoring of the MnO2 nanoparticles on ZIF-8 allows their well disperse to provide more active surface area. Second, highly porous ZIF-8 can adsorb dye molecules to accumulate them at the surface reactive sites. Third, the MnO2/ZIF-8 nano-heterojunctions enhance charge carrier transfer and accelerate the production of free oxidative radicals. The study demonstrates a green method for fabrication of hierarchical hybrid structures, paving the way for designing novel photocatalysts with potential applications for wastewater treatment.
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