石墨
材料科学
插层(化学)
拉曼光谱
石墨烯
电致变色
红外线的
电致变色装置
离子
光电子学
分析化学(期刊)
光学
纳米技术
化学
无机化学
电极
物理
有机化学
复合材料
物理化学
色谱法
作者
Tao Liang,Gang Peng,Xiangzhe Zhang,Yuehua Wei,Xiaoming Zheng,Wenhua Luo,Mengyan Dai,Chuyun Deng,Xueao Zhang
标识
DOI:10.1016/j.optmat.2021.111517
摘要
Two-dimensional materials with optical turnability have wide prospect in related applications such as electrochromic coating and thermal camouflage. Here we report a Li-intercalated ultrathin graphite device with tunable visible-near-infrared reflectivity. After Li-ion intercalation, the Fermi surface of ultrathin graphite will move to a higher level, which prevents the interband optical transitions below it. Therefore, it is possible to change the absorptivity or emissivity of ultrathin graphite through reversible Li-ion intercalation, which accomplishes the modification to reflectivity indirectly. In our experiment, the strong fluorescence background and Peak shifts in Raman spectra, as well as the enlarged layer spacing in XRD spectra, together confirmed that Li-ions were successfully intercalated into the graphite layers. The relative reflectivity of ultrathin graphite increased sharply in a wide range from 460 nm to 1500 nm after complete Li-ion intercalation. At a typical near-infrared wavelength 1500 nm for instance, the relative reflectivity is 0.28 for pristine graphite while 0.70 for fully lithiated graphite. Such reversible intercalated modulation in visible-near-infrared reflectivity of ultrathin graphite might provide a new way to design electrochromic coating, thermal camouflage or radar stealth systems, which also promotes further understanding and optical applications of graphene and other 2D materials.
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