Immobilization of cadmium in contaminated soils using sulfidated nanoscale zero-valent iron: Effectiveness and remediation mechanism

Abstract Sulfidated nanoscale zero-valent iron (S-nZVI) has shown excellent removal capacity for the removal of cadmium (Cd) in aqueous phase. Herein, the effectiveness and the mechanism of S-nZVI for the remediation of Cd contaminated soil were investigated for the first time. The results of sequential extraction procedures (SEP) showed that the exchangeable (EX) Cd was decreased by over 97.6% at the optimal dosage of 5 g kg-1 S-nZVI during 30 d incubation and converted to less available Cd such as iron-manganese oxides-bound (OX) and organic matter-bound (OM) fractions. pH has negligible effect on the immobilization of Cd in soil, since OX fraction was stabilized in the range of 72–92% at initial soil pH range from 5.3 to 7.5. SEM-EDS analysis of the separated magnetic particles implied that Cd was successfully enriched on S-nZVI and the distribution of Cd was closely related to Fe, S, and O. CdO and CdS was confirmed as the key products for Cd immobilization in soil. Meanwhile, the S-nZVI was oxided to α-FeOOH, γ-FeOOH, and γ-Fe2O3. The existence of CdO was visibly related to the iron oxides, suggesting the synergetic immobilization effect by iron oxides. Overall, S-nZVI was promising for the remediation of Cd-contaminated soil.