电致变色
咔唑
利乐
桥接(联网)
接受者
光化学
化学
材料科学
药物化学
电极
计算机科学
物理化学
计算机网络
物理
凝聚态物理
作者
Ceylan Doyranlı,Sinem Altınışık,Mücahit Özdemir,Sermet Koyuncu
标识
DOI:10.1016/j.dyepig.2022.110467
摘要
In this study, a new Donor-Acceptor-Donor (D-A-D) electroactive molecules (HCQM1 and HCQM2) containing 9H-carbazole and 9-phenyl-9H-carbazole as donor along with quinoxaline (HQ) as acceptor were synthesized and then coated on Indium Tin Oxide/Glass (ITO/Glass) surface by the electrochemical oxidation process. The HOMO-LUMO band gap values obtained by electrochemical oxidation and reduction onsets were calculated as 2.64 and 2.68 eV, respectively. On the other hand, UV–Vis absorption measurements showed that the charge transfer band of HCQM1 was detected at 500 nm with 50 nm red shift upon compared with the HCQM2. According to AFM results, it is seen that the roughness of the poly(HCQM2) film is higher than the poly(HCQM1) film. Finally, the polymer film of HCQM2 showed multi-electrochromic color change (yellow, green, and dark blue) upon the oxidation process. When the electrochromic performance of the HCQM1 and HCQM2 polymer films was compared, it was discovered that the HCQM2 with phenylene spacer unit has better stability and a higher percentage transmittance change (ΔT%) between neutral and oxidized states. • Two new Tetra-Carbazole based electroactive donor-acceptor dyes were synthesized. • 50 nm red shift was observed in the absorbtion spectrum between two molecules. • The HOMO-LUMO band gaps were calculated as 2.64 and 2.68 eV, respectively. • Electrochromic performance of HCQM2 has better electrochromic performance than HCQM1.
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