苝
化学
分子
共轭体系
热稳定性
二氯甲烷
酰亚胺
带隙
有机电子学
电化学
富勒烯
光化学
溶剂
高分子化学
聚合物
光电子学
物理化学
有机化学
晶体管
电极
材料科学
电压
物理
量子力学
作者
Muhammad Irfan,Jamaluddin Mahar,Aamer Saeed,Kevin D. Belfield,Muhammad Siddiq
标识
DOI:10.1002/jccs.201700087
摘要
A series of small organic molecules were synthesized by exploiting the bay and imide positions of the perylene nucleus. The synthesized compounds 1 – 11 were characterized by spectroscopic and elemental analyses. These molecules show yellowish color in solution and are highly soluble in dichloromethane. Compound 7 shows a bandgap of 1.7 eV and a Stokes shift of 27. From these results, we infer that this compound can serve as structural template in the design of organic electronics. Moreover, compound 7 shows higher T d (370°C) and T g (132°C) values, which reflect its high thermal stability.
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