材料科学
硅橡胶
热导率
复合材料
电介质
硅酮
复合数
纳米颗粒
弹性体
表面改性
天然橡胶
涂层
环氧树脂
化学工程
纳米技术
工程类
光电子学
作者
Dan Yang,Shuo Huang,Mengnan Ruan,Shuxin Li,Jinwei Yang,Yibo Wu,Weihong Guo,Liqun Zhang
标识
DOI:10.1021/acs.iecr.7b04970
摘要
Inspired by unparalleled adhesion of mussels, bioinspired poly(dopamine) (PDA) has been used to functionalize the surface of aluminum oxide (Al2O3) nanoparticles aiming at improving the thermal conductivity of silicone rubber (SR). The successful and effective preparation of PDA modified Al2O3 nanoparticles (Al2O3–PDA) was confirmed by XPS, HR-TEM, and XRD. The PDA coating on the Al2O3 nanoparticles improved its interfacial interaction between polymeric matrix and facilitated the uniform-dispersion of filler, leading to the 30 vol % Al2O3–PDA/SR composite that exhibited a high thermal conductivity (0.585 W/((m·K))), which was almost 400% of pure silicone rubber (0.147 W/(m·K)). In addition, the 30 vol % Al2O3–PDA/SR composite displayed a relatively low dielectric constant (4.06 at 1 kHz), which was a bit higher than that of pure SR (2.59 at 1 kHz), a big advantage for the electronic or electrical engineering application. With advantages of efficient, easy handling, controllable, and eco-friendly, this modification method provides a new universal route to improve the thermal conductivity of composites.
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