纳米孔
材料科学
表面等离子共振
光催化
等离子体子
纳米结构
纳米技术
扩散
可见光谱
化学工程
X射线光电子能谱
纳米颗粒
光电子学
催化作用
物理
化学
工程类
热力学
生物化学
作者
Da Lü,Shuxin Ouyang,Hua Xu,Dewang Li,Xue Liang Zhang,Yunxiang Li,Jinhua Ye
标识
DOI:10.1021/acsami.6b00889
摘要
Nanoporous single-crystalline SrTiO3 is fabricated at a low temperature of 60 °C via a novel approach of sol–gel alkali-dissolution-exothermal reaction. The plasmon-active metal Au is loaded on the nanoporous single-crystalline SrTiO3 material to construct a new kind of plasmonic photocatalyst. Due to the single-crystalline nature and the space confinement effect of pores for Au growing, not only the promoted diffusion efficiency of surface plasmon resonance (SPR)-induce photoelectron is achieved, but also the diffusion region are well optimized via changing the loading amount of Au. Therefore, an optimal sample with 4.8 wt % Au loading exhibits a more than 40-fold photoactivity enhancement under visible-light irradiation compared to the common nanosized SrTiO3 (a commercially available sample) loaded with 5.3 wt % Au which was prepared under the same condition. Furthermore, combining the special nanostructure of Au surface-modified nanoporous-single-crystalline SrTiO3 with photocatalytic properties, estimation of the diffusion mean free path of SPR-induce photoelectron can be achieved. This study proposes an alternative approach to enhance the photoactivity of plasmonic photocatalyst via fine designing the semiconductor substrate.
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