单体
材料科学
乳液聚合
乳状液
胶粘剂
丙烯酸丁酯
甲基丙烯酸甲酯
高分子化学
丙烯酸
聚合
丙烯酸酯
粒径
化学工程
复合材料
聚合物
图层(电子)
工程类
出处
期刊:China Plastics Industry
日期:2014-01-01
摘要
The acrylic paper-plastic laminating adhesive emulsions were prepared by pre-emulsified semicontinuous emulsion polymerization with butyl acrylate( BA) as soft monomer,methyl methacrylate( MMA)as hard monomer,and acrylic acid( AA) as functional monomer. Effects of hard and soft monomer ratio,the type and amount of emulsifier, initiator dosage and amount of functional monomer on the emulsion properties were investigated. The results showed that the mass ratio of BA:MMA:AA was 80:19:1, the amount of initiator was 0. 7% based on total monomer weight,the emulsifier mass ratio of SDS:OP-10 was1:2. 5,the amount of emulsifier was 3. 5% based on total monomer weight, the emulsion polymerization process was stable and high yield,the prepared emulsion was with small particle size,low viscosity,good stability,and the paper and plastic peel strength can be reached 40. 4 k N / m.
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